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Published: November 11, 2025 | Updated: November 11, 2025By Gangsteel Engineering Team – 25+ Years in Stainless Steel Export Excellence
In the competitive landscape of stainless steels compliant with ASTM A240/A240M and ASME SA240/SA240M standards, comparing 316Ti (titanium-stabilized austenitic) and 321 (niobium-stabilized austenitic) reveals key differences in corrosion resistance, high-temperature performance, and suitability for welded structures.
As a premier producer and exporter based in China, Gangsteel has supplied thousands of tons of both 316Ti and 321 stainless steel, meeting ASTM A240/A240M specs for plates and sheets, to industries such as petrochemical, marine, and power generation.
If you're evaluating 316Ti vs 321 under ASME SA240/SA240M for a heat exchanger or exhaust system where pitting, oxidation, or sensitization risk is critical, this guide provides a clear, data-driven comparison. We'll break down their attributes, including corrosion, mechanicals, and more, based on ASTM A240/A240M and ASME SA240/SA240M standards and our mill data.
From our production lines, we've seen the contrast: In a 2024 European power plant retrofit, our 316Ti tubes under ASTM A240 /A240M resisted pitting in chloride-laden flue gas better than 321, with CPT 25-35°C vs 15-25°C, as per client immersion tests. Compliant with ASME SA240/SA240M for pressure apps, 316Ti's PREN 23-28 vs 321's 18-20 supports chloride-heavy use. Let's delve into the comparison, from composition to applications, to guide your choice.
316Ti and 321 stainless steel under ASTM A240/A240M and ASME SA240/SA240M are both stabilized austenitic grades for high-temp service, but 316Ti's molybdenum (2-3%) provides better pitting and crevice corrosion resistance (PREN 23-28 vs 18-20 for 321), making it ideal for chloride and acid environments. 321's niobium stabilization excels in oxidation and scaling at continuous high temps (up to 925°C intermittent), while 316Ti's Ti is better for welded IGC prevention. Both have tensile 515 MPa min and yield 205 MPa min, but 321 is more formable. Density 8.00 g/cm³ for both. 316Ti costs 5-10% more but offers broader corrosion protection. Choose 316Ti for chlorides/acids, 321 for pure heat. Gangsteel stocks both with certs for custom needs.
The compositions of 316Ti and 321, as per ASTM A240/A240M and ASME SA240/SA240M, show why 316Ti edges in pitting while 321 wins in oxidation.
|
Element |
316Ti (UNS S31635) |
321 (UNS S32100) |
Key Difference Impact |
|---|---|---|---|
|
Carbon (C) |
0.08 max |
0.08 max |
Identical; both low for ductility. |
|
Manganese (Mn) |
2.00 max |
2.00 max |
No difference; deoxidizer. |
|
Silicon (Si) |
0.75 max |
0.75 max |
Identical; oxidation aid. |
|
Phosphorus (P) |
0.045 max |
0.045 max |
No difference. |
|
Sulfur (S) |
0.030 max |
0.030 max |
Identical. |
|
Chromium (Cr) |
16.00-18.00 |
17.00-19.00 |
321 higher for oxidation; 316Ti balanced with Mo. |
|
Molybdenum (Mo) |
2.00-3.00 |
- |
Mo in 316Ti boosts pitting (PREN 23-28 vs 18-20 for 321). |
|
Nickel (Ni) |
10.00-14.00 |
9.00-12.00 |
Higher in 316Ti for acid resistance. |
|
Titanium (Ti) |
5x(C+N) min, 0.70 max |
- |
Ti in 316Ti prevents IGC; 321 uses Nb. |
|
Niobium (Nb) |
- |
5x(C+N) min, 0.70 max |
Nb in 321 for high-temp stabilization. |
|
Nitrogen (N) |
0.10 max |
Not specified |
Minor in 316Ti for strength. |
|
Iron (Fe) |
Balance |
Balance |
Base matrix. |
316Ti's Mo gives it better pitting, while 321's Nb excels in scaling.
Both have similar room-temp properties, but 321 shows better creep at elevated temps.
|
Property |
316Ti Min |
321 Min |
Key Difference |
|---|---|---|---|
|
Tensile Strength (MPa) |
515 |
515 |
Identical; 321 better retention at >600°C. |
|
Yield Strength (MPa) |
205 |
205 |
No difference at room; 321 higher creep. |
|
Elongation (%) |
40 |
40 |
Identical ductility. |
|
Hardness (HRB max) |
95 |
95 |
No difference. |
|
Impact Toughness (J) |
~100 at RT |
~100 at RT |
Similar; both good at low temps. |
321's Nb strengthens at high temps, making it more durable in continuous heat.
Both have similar physicals, but 321's Nb improves high-temp stability.
|
Property |
316Ti Value |
321 Value |
Notes |
|---|---|---|---|
|
Density (g/cm³) |
8.00 |
7.93 |
316Ti slightly denser. |
|
Thermal Conductivity (W/m·K at 100°C) |
14.6 |
15.0 |
Minor difference. |
|
Specific Heat (J/kg·K) |
500 |
500 |
Identical. |
|
Thermal Expansion (10^-6 /°C, 20-100°C) |
16.5 |
16.5 |
Low for both. |
316Ti's lower expansion enhances durability in thermal cycling.
Both resist general corrosion well, but 316Ti's Mo provides better pitting, while 321's Nb excels in scaling.
316Ti is more versatile for corrosives; 321 for pure oxidation.
Both weld well with fillers like ER316L; no preheat. 316Ti's Ti prevents IGC at heat, 321's Nb for scaling. Machinability ~60% for both.
Gangsteel's 316Ti SA240 Type 316Ti offers superior weld performance.
In Gangsteel's supply to U.S. marine, 316Ti lasted longer in salt.
316Ti equivalents: EN 1.4571. 321 equivalents: EN 1.4541. For A240 GR 316Ti, not interchangeable with 321 in chlorides.
Gangsteel stocks 316Ti and 321 at $3,200-3,800/ton (316Ti) and $3,000-3,500 (321) FOB. 1-200mm thick, certs. Contact for comparisons.
Q: How does corrosion resistance compare between 316Ti and 321 stainless steel?
A: 316Ti has superior pitting/crevice resistance (PREN 23-28 vs 18-20) due to Mo, while 321 excels in oxidation/scaling at high temps from Nb; both good IGC with stabilizers.
Q: What are the mechanical property differences between 316Ti and 321?
A: Both have tensile 515 MPa min and yield 205 MPa min, but 321 shows better creep at >600°C due to Nb, while 316Ti has higher pitting strength.
Q: Which is better for high-temperature applications, 316Ti or 321?
A: 321 is better for continuous high-temp oxidation (up to 925°C intermittent), while 316Ti excels in welded IGC resistance and chlorides due to Mo.
Q: How do pitting and crevice corrosion compare for 316Ti and 321?
A: 316Ti is superior with CPT 25-35°C vs 15-25°C for 321, thanks to Mo; 321's Nb doesn't enhance pitting.
Q: Is 316Ti or 321 more cost-effective for high-temperature apps?
A: 316Ti for chlorides/acids (higher initial cost but better pitting); 321 for pure oxidation (lower cost, similar heat stability).
Q: What is the PREN of 316Ti vs 321 stainless steel?
A: 316Ti PREN 23-28 (Mo boost); 321 ~18-20—no Mo, lower pitting.
Q: Can I substitute 321 for 316Ti in corrosion apps?
A: Yes for high-temp oxidation, but not for chlorides where 316Ti's Mo is essential; check specs for equivalence.
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