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316Ti Stainless Steel 321 vs 316Ti Comparison

Published: November 11, 2025 | Updated: November 11, 2025By Gangsteel Engineering Team – 25+ Years in Stainless Steel Export Excellence

In the competitive landscape of stainless steels compliant with ASTM A240/A240M and ASME SA240/SA240M standards, comparing 316Ti (titanium-stabilized austenitic) and 321 (niobium-stabilized austenitic) reveals key differences in corrosion resistance, high-temperature performance, and suitability for welded structures.

As a premier producer and exporter based in China, Gangsteel has supplied thousands of tons of both 316Ti and 321 stainless steel, meeting ASTM A240/A240M specs for plates and sheets, to industries such as petrochemical, marine, and power generation.

If you're evaluating 316Ti vs 321 under ASME SA240/SA240M for a heat exchanger or exhaust system where pitting, oxidation, or sensitization risk is critical, this guide provides a clear, data-driven comparison. We'll break down their attributes, including corrosion, mechanicals, and more, based on ASTM A240/A240M and ASME SA240/SA240M standards and our mill data.

From our production lines, we've seen the contrast: In a 2024 European power plant retrofit, our 316Ti tubes under ASTM A240 /A240M resisted pitting in chloride-laden flue gas better than 321, with CPT 25-35°C vs 15-25°C, as per client immersion tests. Compliant with ASME SA240/SA240M for pressure apps, 316Ti's PREN 23-28 vs 321's 18-20 supports chloride-heavy use. Let's delve into the comparison, from composition to applications, to guide your choice.

 

Summary

316Ti and 321 stainless steel under ASTM A240/A240M and ASME SA240/SA240M are both stabilized austenitic grades for high-temp service, but 316Ti's molybdenum (2-3%) provides better pitting and crevice corrosion resistance (PREN 23-28 vs 18-20 for 321), making it ideal for chloride and acid environments. 321's niobium stabilization excels in oxidation and scaling at continuous high temps (up to 925°C intermittent), while 316Ti's Ti is better for welded IGC prevention. Both have tensile 515 MPa min and yield 205 MPa min, but 321 is more formable. Density 8.00 g/cm³ for both. 316Ti costs 5-10% more but offers broader corrosion protection. Choose 316Ti for chlorides/acids, 321 for pure heat. Gangsteel stocks both with certs for custom needs.

 

Chemical Composition: The Key Differentiator

The compositions of 316Ti and 321, as per ASTM A240/A240M and ASME SA240/SA240M, show why 316Ti edges in pitting while 321 wins in oxidation.

Element

316Ti (UNS S31635)

321 (UNS S32100)

Key Difference Impact

Carbon (C)

0.08 max

0.08 max

Identical; both low for ductility.

Manganese (Mn)

2.00 max

2.00 max

No difference; deoxidizer.

Silicon (Si)

0.75 max

0.75 max

Identical; oxidation aid.

Phosphorus (P)

0.045 max

0.045 max

No difference.

Sulfur (S)

0.030 max

0.030 max

Identical.

Chromium (Cr)

16.00-18.00

17.00-19.00

321 higher for oxidation; 316Ti balanced with Mo.

Molybdenum (Mo)

2.00-3.00

-

Mo in 316Ti boosts pitting (PREN 23-28 vs 18-20 for 321).

Nickel (Ni)

10.00-14.00

9.00-12.00

Higher in 316Ti for acid resistance.

Titanium (Ti)

5x(C+N) min, 0.70 max

-

Ti in 316Ti prevents IGC; 321 uses Nb.

Niobium (Nb)

-

5x(C+N) min, 0.70 max

Nb in 321 for high-temp stabilization.

Nitrogen (N)

0.10 max

Not specified

Minor in 316Ti for strength.

Iron (Fe)

Balance

Balance

Base matrix.

316Ti's Mo gives it better pitting, while 321's Nb excels in scaling.

 

Mechanical Properties: Comparable with Edges

Both have similar room-temp properties, but 321 shows better creep at elevated temps.

Property

316Ti Min

321 Min

Key Difference

Tensile Strength (MPa)

515

515

Identical; 321 better retention at >600°C.

Yield Strength (MPa)

205

205

No difference at room; 321 higher creep.

Elongation (%)

40

40

Identical ductility.

Hardness (HRB max)

95

95

No difference.

Impact Toughness (J)

~100 at RT

~100 at RT

Similar; both good at low temps.

321's Nb strengthens at high temps, making it more durable in continuous heat.

 

Physical Properties: Minor Variations

Both have similar physicals, but 321's Nb improves high-temp stability.

Property

316Ti Value

321 Value

Notes

Density (g/cm³)

8.00

7.93

316Ti slightly denser.

Thermal Conductivity (W/m·K at 100°C)

14.6

15.0

Minor difference.

Specific Heat (J/kg·K)

500

500

Identical.

Thermal Expansion (10^-6 /°C, 20-100°C)

16.5

16.5

Low for both.

316Ti's lower expansion enhances durability in thermal cycling.

 

Corrosion Resistance: 316Ti's Pitting Edge

Both resist general corrosion well, but 316Ti's Mo provides better pitting, while 321's Nb excels in scaling.

  • Pitting/Crevice: 316Ti superior with Mo (PREN 23-28 vs 18-20 for 321); CPT ~25°C vs 15°C.
  • IGC: Both resistant (316Ti Ti, 321 Nb).
  • SCC: Both good; 316Ti better in chlorides.
  • Uniform: <0.1 mm/year in dilute acids; similar.
  • High-Temp: 321 better for scaling; 316Ti for IGC in welds.

316Ti is more versatile for corrosives; 321 for pure oxidation.

Weldability and Fabrication: Similar Ease

Both weld well with fillers like ER316L; no preheat. 316Ti's Ti prevents IGC at heat, 321's Nb for scaling. Machinability ~60% for both.

Gangsteel's 316Ti SA240 Type 316Ti offers superior weld performance.

Applications: Overlapping but Specialized

  • Common: Heat exchangers (both durable).
  • 316Ti Specific: Marine, chemical (pitting in chlorides).
  • 321 Specific: Aerospace, exhausts (oxidation at heat).

In Gangsteel's supply to U.S. marine, 316Ti lasted longer in salt.

Equivalents: Alternatives for Both

316Ti equivalents: EN 1.4571. 321 equivalents: EN 1.4541. For A240 GR 316Ti, not interchangeable with 321 in chlorides.

 

Sourcing from Gangsteel: Stock and Pricing

Gangsteel stocks 316Ti and 321 at $3,200-3,800/ton (316Ti) and $3,000-3,500 (321) FOB. 1-200mm thick, certs. Contact for comparisons.

 

FAQ: 316Ti vs 321 Stainless Steel Questions Answered

Q: How does corrosion resistance compare between 316Ti and 321 stainless steel?

A: 316Ti has superior pitting/crevice resistance (PREN 23-28 vs 18-20) due to Mo, while 321 excels in oxidation/scaling at high temps from Nb; both good IGC with stabilizers.

Q: What are the mechanical property differences between 316Ti and 321?

A: Both have tensile 515 MPa min and yield 205 MPa min, but 321 shows better creep at >600°C due to Nb, while 316Ti has higher pitting strength.

Q: Which is better for high-temperature applications, 316Ti or 321?

A: 321 is better for continuous high-temp oxidation (up to 925°C intermittent), while 316Ti excels in welded IGC resistance and chlorides due to Mo.

Q: How do pitting and crevice corrosion compare for 316Ti and 321?

A: 316Ti is superior with CPT 25-35°C vs 15-25°C for 321, thanks to Mo; 321's Nb doesn't enhance pitting.

Q: Is 316Ti or 321 more cost-effective for high-temperature apps?

A: 316Ti for chlorides/acids (higher initial cost but better pitting); 321 for pure oxidation (lower cost, similar heat stability).

Q: What is the PREN of 316Ti vs 321 stainless steel?

A: 316Ti PREN 23-28 (Mo boost); 321 ~18-20—no Mo, lower pitting.

Q: Can I substitute 321 for 316Ti in corrosion apps?

A: Yes for high-temp oxidation, but not for chlorides where 316Ti's Mo is essential; check specs for equivalence.

 

 

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